Preheat the oven to 175°C conventional (or 155°C fan-forced).
Grease 2 mini loaf pans (8 holes each). Cut out baking paper to snuggly fit into the base of each hole, to prevent the cakes from sticking.
In a medium heatproof bowl, combine the cocoa powder and espresso powder. Pour over the boiling water and whisk to combine. Set aside to cool to room temperature.
In a large mixing bowl, sift together the flour, baking powder, baking soda, salt, white sugar, and brown sugar. I use a coarse sieve—it’s easier with the brown sugar. Pass the mix through the sieve at least twice until the texture is even and fine, like soft sand.
In a separate jug, whisk the sour cream, then add the eggs one at a time, beating well after each addition. Whisk in the grapeseed oil and vanilla extract. Then add the cooled cocoa and espresso mixture and whisk until fully combined.
Add the wet ingredients to the dry in three batches. Use a balloon to whisk in each addition, adding the next batch as soon as the previous is mostly incorporated. After the final addition, give it one last gentle whisk—don’t overmix.
Divide the batter evenly to create 14 mini cakes—around 80g per cake. Tap the pans gently on the bench to release any air bubbles.
Bake for 12-14 minutes (start checking at 12). The cakes are done when a skewer or cake tester comes out clean with a few moist crumbs.
Cool the cakes completely in their tins on a cooling rack until completely cool, then gently remove form the pan and chill until ready to decorate with ganache.