Preheat the oven to 175°C conventional (or 155°C fan-forced).
Grease and line three 20 cm (8-inch) round cake tins. If using baking strips or cake collars, soak them in water and secure around the tins with bulldog clips.
In a medium heatproof bowl, combine the cocoa powder and espresso powder. Pour over the boiling water and whisk to combine. Set aside to cool to room temperature.
In a large mixing bowl, sift together the flour, baking powder, baking soda, salt, white sugar, and brown sugar. I use a coarse sieve—it’s easier with the brown sugar. Pass the mix through the sieve at least twice until the texture is even and fine, like soft sand.
In a separate jug, whisk the sour cream, then add the eggs one at a time, beating well after each addition. Whisk in the grapeseed oil and vanilla extract. Then add the cooled cocoa and espresso mixture and whisk until fully combined.
Add the wet ingredients to the dry in three batches. Use a balloon to whisk in each addition, adding the next batch as soon as the previous is mostly incorporated. After the final addition, give it one last gentle whisk—don’t overmix.
Divide the batter evenly between the three pans—around 790g to 800g per tin. Tap the pans gently on the bench to release any air bubbles.
Bake for 40–44 minutes with collars (start checking at 35), or 25–28 minutes without. The cakes are done when a skewer or cake tester comes out clean with a few moist crumbs.
Cool the cakes in their tins for 10 minutes before turning out onto racks to cool completely.